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Journal Article 135

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Highly selective detection of copper(II) by a “ligand-free” conjugated copolymer in nucleophilic solvents

Weixing Deng, Pengfei Sun, Quli Fan, Lei Zhang, Tsuyoshi Minami

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 1,   Pages 105-111 doi: 10.1007/s11705-019-1791-6

Abstract: -cyclohexyl carbamate-attached fluorene- -phenylene copolymer (PFPNCC) and the use of PFPNCC as a “ligand-freestrategy for highly selective conjugated polymer-based chemosensors for various target analytes, albeit “ligand-free

Keywords: ligand-free     fluorescent chemosensor     copper     photo-induced electron transfer    

Effects of ancillary ligands in acceptorless benzyl alcohol dehydrogenation mediated by phosphine-free

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 3,   Pages 314-325 doi: 10.1007/s11705-022-2219-2

Abstract: Among various catalytic systems for this reaction, cost-effective molecular catalysts using phosphine-freeHerein, we synthesized a phosphine-free η5-C5Me5-Co complex by usingThe results showed that the redox-active ligand has a significant influence on the η5-C5-C5Me5 ligand playedrationales for designing metal–ligand cooperative nonprecious metal complexes.

Keywords: acceptorless alcohol dehydrogenation     η5-C5Me5-Co     metal–ligand cooperation    

Surface modification by ligand growth strategy for dense copper bismuth film as photocathode to enhance

Frontiers in Energy doi: 10.1007/s11708-023-0893-5

Abstract: Herein, a straightforward sol-gel method with the ligand-induced growth strategy was employed to obtainthe nucleation and surface growth of CuBi2O4 layer induced by 2-methoxyethanol ligandThis surface modification by ligand growth strategy will shed light on the future design of advanced

Keywords: copper bismuthate     photocathode     ligand growth strategy     dense film     PEC    

Synthesis of vinylferrocene and the ligand-exchange reaction between its copolymer and carbon nanotubes

Ran SHI,Hai WANG,Ping TANG,Yuezhen BIN

Frontiers of Chemical Science and Engineering 2014, Volume 8, Issue 2,   Pages 171-178 doi: 10.1007/s11705-014-1428-8

Abstract: nanotubes (CNTs), poly(vinylferrocene- -styrene) (poly(Vf- -St)), was grafted onto the surface of CNTs by a ligand-exchange

Keywords: vinylferrocene     poly (Vf-co-St)     CNTs     dispersibility    

Effect of ligand chain length on hydrophobic charge induction chromatography revealed by molecular dynamics

Lin ZHANG, Yan SUN

Frontiers of Chemical Science and Engineering 2013, Volume 7, Issue 4,   Pages 456-463 doi: 10.1007/s11705-013-1357-y

Abstract: The effect of the ligand chain length on protein behavior in HCIC was studied.The ligand chain length has a significant effect on both the probability and the irreversibility of theThe simulation results elucidated the effect of the ligand chain length, which is beneficial for the

Keywords: adsorption     desorption     irreversibility     protein conformational transition     molecular dynamics simulation    

BGB-A445, a novel non-ligand-blocking agonistic anti-OX40 antibody, exhibits superior immune activation

Frontiers of Medicine doi: 10.1007/s11684-023-0996-8

Abstract: The ligation of OX40 to its sole ligand OX40L potentiates T cell expansion, differentiation, and activationHere, we discovered that BGB-A445, a non-ligand-competitive agonistic anti-OX40 antibody currently underOX40 knock-in mice, BGB-A445 demonstrated robust and dose-dependent antitumor efficacy, whereas the ligand-competitive

Keywords: BGB-A445     OX40     agonistic antibody     OX40L noncompetitive    

Cell-free systems in the new age of synthetic biology

Fernando Villarreal,Cheemeng Tan

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 1,   Pages 58-65 doi: 10.1007/s11705-017-1610-x

Abstract: The advent of synthetic biology has ushered in new applications of cell-free transcription-translationThese cell-free systems are reconstituted using cellular proteins, and are amenable to modular controlHere, we discuss the historical advancement of cell-free systems, as well as their new applications inFinally, we present our vision on the future direction of cell-free synthetic biology.

Keywords: cell-free system     application    

Fabrication of recyclable Fe chelated aminated polypropylene fiber for efficient clean-up of phosphate wastewater

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 7,   Pages 840-852 doi: 10.1007/s11705-022-2253-0

Abstract: Herein, a Fe3+-loaded aminated polypropylene fiber has been reported as an efficient phosphate adsorbent. The remarkable phosphate removal ability of the fiber is due to Fe3+ immobilization, and it demonstrates a maximum adsorption capacity of 33.94 mg·P·g–1. Adsorption experiments showed that the fiber is applicable over a wide pH range from 2 to 9. Furthermore, the adsorption kinetics and isotherm data were consistent with the pseudo-second-order and Langmuir adsorption models, respectively. The adsorption equilibrium of the fiber for phosphate was reached within 60 min, indicating an efficient monolayer chemisorption process. Moreover, the adsorbent maintained prominent phosphate removal in the presence of competitive ions such as NO3 and Cl, exhibiting high selectivity. More importantly, the fiber demonstrated excellent reusability (5 times) and low adsorption limit below 0.02 mg·P·g–1. In addition, the phosphate removal efficiency of the fiber can exceed 99% under continuous flow conditions. The adsorption mechanism was studied by X-ray photoelectron spectroscopy, showing that the adsorption of phosphate on the fiber mainly depended on the chemical adsorption of the modified Fe3+. Overall, this study proves that the fiber possesses many advantages for phosphate removal, including high adsorption efficiency, lower treatment limit, good recyclability, and environmental friendliness.

Keywords: phosphate adsorption     aminated polypropylene fiber     Fe3+     ligand exchange     reusability    

The Application of Artificial Intelligence Accelerates G Protein-Coupled Receptor Ligand Discovery Review

Wei Chen,Chi Song,Liang Leng,Sanyin Zhang,Shilin Chen

Engineering 2024, Volume 32, Issue 1,   Pages 19-29 doi: 10.1016/j.eng.2023.09.011

Abstract: However, traditional approaches to GPCR ligand discovery are time-consuming and resource-intensive.The emergence of artificial intelligence (AI) methods has revolutionized the field of GPCR ligand discoveryIn this study, we provide guidelines for effectively utilizing AI methods for GPCR ligand discovery,First, the online resources that are instrumental in GPCR ligand discovery were summarized, includingdatabases and repositories that contain valuable GPCR-related information and ligand data.

Keywords: G protein-coupled receptor     Ligand     Artificial intelligence     Multi-omics     Drug discovery    

Recent advances in cycloaddition of CO with epoxides: halogen-free catalysis and mechanistic insights

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 12,   Pages 1879-1894 doi: 10.1007/s11705-023-2354-4

Abstract: To address these concerns, the halogen-free cycloaddition of CO2 with epoxides has alwaysIn this review, we systematically discussed the halogen-free catalysis for cycloaddition of CO2freeSpecially, metal oxides as the potential halogen-free catalysts are highlighted due to their flexible

Keywords: carbon dioxide     halogen-free catalysis     cyclic carbonate     mechanistic insight    

Hollow carbon spheres and their noble metal-free hybrids in catalysis

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1380-1407 doi: 10.1007/s11705-021-2097-z

Abstract: Herein, we overview hollow carbon sphere-based materials and their noble metal-free hybrids in catalysiscontrolling pore structure and surface morphology, and then heterogeneous doping as well as their metal-free

Keywords: hollow carbon spheres     functionalization     noble metal-free     catalysis    

Decontamination of Cr(VI) facilitated formation of persistent free radicals on rice husk derived biochar

Kaikai Zhang, Peng Sun, Yanrong Zhang

Frontiers of Environmental Science & Engineering 2019, Volume 13, Issue 2, doi: 10.1007/s11783-019-1106-7

Abstract:

PFRs were produced on biochar during Cr(VI) decontamination.

PFRs formation on biochar was owing to the oxidization of phenolic-OH by Cr(VI).

Appearance of excessive oxidant led to the consumption of PFRs on biochar.

Biochar charred at high temperature possessed great performance to Cr(VI) removal.

Keywords: Biochar     Persistent free radicals     Phenolic hydroxyl groups     Cr(VI) reduction    

Thermoresponsive block copolymer supported Pt nanocatalysts for base-free aerobic oxidation of 5-hydroxymethyl

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1514-1523 doi: 10.1007/s11705-021-2092-4

Abstract: A base-free catalytic system for the aerobic oxidation of 5-hydroxymethyl-2-furfural was exploited byThe Pt nanocatalysts were well-dispersed and highly active for the base-free oxidation of 5-hydroxymethyl

Keywords: aerobic oxidation     base-free     5-hydroxymethyl-2-furfural     Pt nanoparticle     thermoresponsive block copolymer    

Influence of the filler materials on flux-free brazing of pure aluminium (1050)

Kirsten BOBZIN, Lidong ZHAO, Thomas SCHLAEFER, Thomas WARDA,

Frontiers of Mechanical Engineering 2010, Volume 5, Issue 1,   Pages 47-51 doi: 10.1007/s11465-009-0079-9

Abstract: Al7Si, Al12Si-4%Cu, and the Al-Si-based filler material A, which was especially developed for flux-free

Keywords: aluminium     flux-free brazing     cold spraying     shear strength    

New perspectives in free nitrous acid (FNA) uses for sustainable wastewater management

Frontiers of Environmental Science & Engineering 2023, Volume 18, Issue 2, doi: 10.1007/s11783-024-1786-5

Abstract:

● The historical development of free nitrous acid (FNA) technologies

Keywords: Free nitrous acid     Acid-tolerant ammonia oxidizer     In situ generation     Wastewater management    

Title Author Date Type Operation

Highly selective detection of copper(II) by a “ligand-free” conjugated copolymer in nucleophilic solvents

Weixing Deng, Pengfei Sun, Quli Fan, Lei Zhang, Tsuyoshi Minami

Journal Article

Effects of ancillary ligands in acceptorless benzyl alcohol dehydrogenation mediated by phosphine-free

Journal Article

Surface modification by ligand growth strategy for dense copper bismuth film as photocathode to enhance

Journal Article

Synthesis of vinylferrocene and the ligand-exchange reaction between its copolymer and carbon nanotubes

Ran SHI,Hai WANG,Ping TANG,Yuezhen BIN

Journal Article

Effect of ligand chain length on hydrophobic charge induction chromatography revealed by molecular dynamics

Lin ZHANG, Yan SUN

Journal Article

BGB-A445, a novel non-ligand-blocking agonistic anti-OX40 antibody, exhibits superior immune activation

Journal Article

Cell-free systems in the new age of synthetic biology

Fernando Villarreal,Cheemeng Tan

Journal Article

Fabrication of recyclable Fe chelated aminated polypropylene fiber for efficient clean-up of phosphate wastewater

Journal Article

The Application of Artificial Intelligence Accelerates G Protein-Coupled Receptor Ligand Discovery

Wei Chen,Chi Song,Liang Leng,Sanyin Zhang,Shilin Chen

Journal Article

Recent advances in cycloaddition of CO with epoxides: halogen-free catalysis and mechanistic insights

Journal Article

Hollow carbon spheres and their noble metal-free hybrids in catalysis

Journal Article

Decontamination of Cr(VI) facilitated formation of persistent free radicals on rice husk derived biochar

Kaikai Zhang, Peng Sun, Yanrong Zhang

Journal Article

Thermoresponsive block copolymer supported Pt nanocatalysts for base-free aerobic oxidation of 5-hydroxymethyl

Journal Article

Influence of the filler materials on flux-free brazing of pure aluminium (1050)

Kirsten BOBZIN, Lidong ZHAO, Thomas SCHLAEFER, Thomas WARDA,

Journal Article

New perspectives in free nitrous acid (FNA) uses for sustainable wastewater management

Journal Article